Laudanidine
Code | Size | Price |
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TAR-T32589-5mg | 5mg | £850.00 | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Overview
Regulatory Status: RUO
Shipping:
cool pack
Storage:
-20℃
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Further Information
Bioactivity:
Laudanidine is a nitrile-stabilized ammonium ylide.
CAS:
301-21-3
Formula:
C20H25NO4
Molecular Weight:
343.423
Purity:
0.98
SMILES:
COc1ccc(C[C@H]2N(C)CCc3cc(OC)c(OC)cc23)cc1O
References
1. Orejarena Pacheco JC, Lahm G, Opatz T. Synthesis of alkaloids by Stevens rearrangement of nitrile-stabilized ammonium ylides: (?)-laudanosine, (?)-laudanidine, (?)-armepavine, (?)-7-methoxycryptopleurine, and (?)-xylopinine. J Org Chem. 2013 May 17;78(10):4985-92. doi: 10.1021/jo400659n. Epub 2013 May 9. PubMed PMID: 23634947.
2. Blank N, Opatz T. Enantioselective synthesis of tetrahydroprotoberberines and bisbenzylisoquinoline alkaloids from a deprotonated ?-aminonitrile. J Org Chem. 2011 Dec 2;76(23):9777-84. doi: 10.1021/jo201871c. Epub 2011 Oct 26. PubMed PMID: 22004161.
3. Blanchfield JT, Sands DP, Kennard CH, Byriel KA, Kitching W. Characterisation of alkaloids from some Australian Stephania (Menispermaceae) species. Phytochemistry. 2003 Jul;63(6):711-20. PubMed PMID: 12842145.
4. Kanokmedhakul S, Kanokmedhakul K, Lekphrom R. Bioactive constituents of the roots of Polyalthia cerasoides. J Nat Prod. 2007 Sep;70(9):1536-8. Epub 2007 Sep 11. PubMed PMID: 17845001.