Chemodex

1-Hydroxy-1,2-benziodoxol-3-one 1-oxide pyridinium complex

Product Code:
 
CDX-H0104
Product Group:
 
Other Biochemicals
Supplier:
 
Chemodex
Regulatory Status:
 
RUO
Shipping:
 
Ambient
Storage:
 
Short term: +4°C. Long term: -20°C
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Chemical Structure
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Chemical Structure

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Further Information

Alternate Names/Synonyms:
IBX pyridine complex; PIBX; Pyridinium o-iodoxybenzoate
Appearance:
White to off-white solid.
CAS:
1380548-11-7
EClass:
32160000
Form (Short):
liquid
GHS Symbol:
GHS07
Handling Advice:
Keep cool and dry.Protect from light and moisture.
Hazards:
H302, H312, H332, H315, H319, H335
InChi:
InChI=1S/C7H5IO4.C5H5N/c9-7-5-3-1-2-4-6(5)8(10,11)12-7;1-2-4-6-5-3-1/h1-4H,(H,10,11);1-5H
InChiKey:
JKZNBOGIALICGN-UHFFFAOYSA-N
Long Description:
Chemical. CAS: 1380548-11-7. Formula: C12H10INO4. MW: 359.1. Synthetic. Stable pyridinium salt of o-iodoxybenzoic acid (PIBX) is a convenient substitute of o-iodoxybenzoic acid (IBX) as an oxidant. PIBX is safer, has neutral properties behaves as an equivalent to IBX in the oxidation of alcohols to ketones or aldehydes in polar solvents and provides higher oxidation rate in THF due to better solubility.
MDL:
MFCD28100471
Molecular Formula:
C12H10INO4
Molecular Weight:
359.1
Package Type:
Vial
Precautions:
P261, P280, P305, P351, P338
Product Description:
Stable pyridinium salt of o-iodoxybenzoic acid (PIBX) is a convenient substitute of o-iodoxybenzoic acid (IBX) as an oxidant. PIBX is safer, has neutral properties behaves as an equivalent to IBX in the oxidation of alcohols to ketones or aldehydes in polar solvents and provides higher oxidation rate in THF due to better solubility.
Purity:
>97% (NMR)
Signal word:
Warning
SMILES:
C1=CC=[NH+]C=C1.[O-][I]1(=O)OC(=O)C2=CC=CC=C12
Solubility Chemicals:
Soluble in toluene.
Source / Host:
Synthetic.
Transportation:
Non-hazardous
UNSPSC Category:
Biochemical Reagents
UNSPSC Number:
12352200
Use & Stability:
Stable for at least 2 years after receipt when stored at -20°C.

References

(1) I.M. Kumanyaev, et al.; Mendeleev Commun. 22, 129 (2012)