Ru(bpy)2(phen-5-NH2)(PF6)2
| Code | Size | Price |
|---|
| CDX-B0671-M005 | 5 mg | £184.00 |
Quantity:
Prices exclude any Taxes / VAT
Overview
Regulatory Status: RUO
Shipping:
Ambient
Storage:
Short term: -20°C. Long term: -20°C
Documents
Further Information
Alternate Names/Synonyms:
Bis-(2,2'-bipyridin)-(5-amino-phenanthrolin)ruthenium bis(hexafluorophosphat)
Appearance:
Red to dark purple powder.
CAS:
84537-86-0
EClass:
32160000
Form (Short):
solid
Handling Advice:
Protect from light and moisture.
InChi:
InChi=1S/C12H9N3.2C10H8N2.2F6P.Ru/c13-10-7-8-3-1-5-14-11(8)12-9(10)4-2-6-15-12;2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2*1-7(2,3,4,5)6;/h1-7H,13H2;2*1-8H;;;/q;;;2*-1;+2
InChiKey:
QQMMCXKCYXQNNA-UHFFFAOYSA-N
Long Description:
Chemical. CAS: 84537-86-0. Formula: C32H25N7Ru . 2PF6. MW: 898.59. Ru(bpy)2(phen-5-NH2)(PF6)2 is a fluorescent metal-ligand complex probe. It shows high brightness and large Stokes Shift. Spectral Data: lambdaex=458nm; lambdaem=612nm in 0.1 M Tris pH 7.0. It has been used as starting material for synthesis of long-lifetime luminescent Ru complexes and in the preparation of amino-ruthenium(ii) complex functionalized gold nanoparticles, which could be used as probe in biosensors and bioassays. Ru(bpy)2(phen-5-NH2)(PF6)2 is has also been used to synthesize fluorescent silica nanoparticles with ultrabrightness and photostability by encapsulating it into silica nanoparticles by a modified reversed microemulsion method. Could be used for the determination of nucleotide base sequences.
MDL:
MFCD20921517
Molecular Formula:
C32H25N7Ru . 2PF6
Molecular Weight:
898.59
Package Type:
Vial
Product Description:
Ru(bpy)2(phen-5-NH2)(PF6)2 is a fluorescent metal-ligand complex probe. It shows high brightness and large Stokes Shift. Spectral Data: lambdaex=458nm; lambdaem=612nm in 0.1 M Tris pH 7.0. It has been used as starting material for synthesis of long-lifetime luminescent Ru complexes and in the preparation of amino-ruthenium(ii) complex functionalized gold nanoparticles, which could be used as probe in biosensors and bioassays. Ru(bpy)2(phen-5-NH2)(PF6)2 is has also been used to synthesize fluorescent silica nanoparticles with ultrabrightness and photostability by encapsulating it into silica nanoparticles by a modified reversed microemulsion method. Could be used for the determination of nucleotide base sequences.
Purity:
>95% (NMR)
SMILES:
C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC2=CC(=C3C=CC=NC3=C2N=C1)N.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.[Ru+2]
[F-][P+5]([F-])([F-])([F-])([F-])[F-].NC1=CC2=CC=C[N]3=C2C=4C1=CC=C[N]4[Ru+2]563([N]=7C=CC=CC7C=8C=CC=C[N]85)[N]=9C=CC=CC9C=%10C=CC=C[N]%106
Solubility Chemicals:
Soluble in DMSO.
Source / Host:
Synthetic
Transportation:
Non-hazardous
UNSPSC Number:
41105331
Use & Stability:
Stable for at least 2 years after receipt when stored at -20°C.
References
(1) C.D. Ellis, et at.; Inorg. Chem. 22, 1283 (1983) | (2) E. Terpetschnig, et al.; Anal. Biochem. 251, 241 (1997) | (3) F.N. Castellano et al.; Anal. Bioch. 255, 165 (1998) | (4) J.H. Snook, et al.; Org. Electron. 6, 55 (2005) | (5) J. Weh, et al.; ChemBioChem 8, 122 (2007) | (6) Y. Yu, et al.; J. Mat. Chem. 21, 12622 (2011) | (7) E. de la Llave, et al.; J. Phys. Chem. C 118, 21420 (2014) | (8) D. Lu, et al.; RSC Adv. 6, 51597 (2016) | (9) T. Wang, et al.; Anal. Chim. Acta 1062, 124 (2019) | (10) D. Bahari, et al.; Anal. Chim. Acta 1132, 55 (2020)