Chemodex

1,1-Bis(phenylsulfonyl)ethylene

Product Code:
 
CDX-B0127
Product Group:
 
Other Biochemicals
Supplier:
 
Chemodex
Regulatory Status:
 
RUO
Shipping:
 
Ambient
Storage:
 
Short term: +4°C. Long term: -20°C
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Chemical Structure
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Chemical Structure

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CDX-B0127-G0011 g£79.00
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CDX-B0127-G0055 g£305.00
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Further Information

Alternate Names/Synonyms:
1,1-Bis(benzenesulfonyl)ethylene
Appearance:
White to faint yellow powder.
CAS:
39082-53-6
EClass:
32160000
Form (Short):
liquid
Handling Advice:
Keep cool and dry.Protect from light and moisture.
InChi:
InChI=1S/C14H12O4S2/c1-12(19(15,16)13-8-4-2-5-9-13)20(17,18)14-10-6-3-7-11-14/h2-11H,1H2
InChiKey:
KABQEPJVQFXVIN-UHFFFAOYSA-N
Long Description:
Chemical. CAS: 39082-53-6. Formula: C14H12O4S2. MW: 308.4. Synthetic. Synthetic compound equivalent to the ethylene 1,2-dipole. Dienophile used for Diels-Alder reactions and useful synthon for neutral homologation of ketones. Used in the preparation of alpha,alpha-disubstituted alpha-amino acid derivatives.
MDL:
MFCD00043149
Molecular Formula:
C14H12O4S2
Molecular Weight:
308.4
Package Type:
Vial
Product Description:
Synthetic compound equivalent to the ethylene 1,2-dipole. Dienophile used for Diels-Alder reactions and useful synthon for neutral homologation of ketones. Used in the preparation of alpha,alpha-disubstituted alpha-amino acid derivatives.
Purity:
>98% (HPLC)
SMILES:
C=C(S(=O)(=O)C1=CC=CC=C1)S(=O)(=O)C1=CC=CC=C1
Solubility Chemicals:
Soluble in toluene.
Source / Host:
Synthetic.
Transportation:
Non-hazardous
UNSPSC Category:
Biochemical Reagents
UNSPSC Number:
12352200
Use & Stability:
Stable for at least 2 years after receipt when stored at -20°C.

References

(1) O. De Lucchi, et al.; Tetrahedron Lett. 25, 3643, (1984) | (2) O. De Lucchi, et al.; Tetrahedron Lett. 25, 3647, (1984) | (3) O. De Lucchi, et al.; Zeitschr.f. Kristallogr. 170, 267 (1985) | (4) A.N. Alba, et al.; Chemistry 16, 5354 (2010) | (5) R.L. Atienza & K.A. Scheidt; Aust. J. Chem. 64, 1158 (2011)